I've got a few suggestions, depending on what you like.
A good indie rock album (I guess that's how you'd describe it) is the first Between the Trees album, The Story and the Song. http://www.youtube.com/watch?v=4nuG0GvzF8k
An indie band called Wolf Parade is also pretty good. http://www.youtube.com/watch?v=ktu_vAzhYcs (This video isn't the whole song, but you can look up the full version)
It got slightly popular, but the most recent The Killers album is also worth a look. It was the first album I didn't rip from a friend's cd, and it's still one of my favorite albums.
http://www.youtube.com/watch?v=v0WV5RHNYKg
If you're looking for a little prog rock, a good one is the aforementioned Rush, but I'd also suggest Jethro Tull (folk-prog), Glass Hammer (I think Symphonic Prog is the classification, maybe Hard Prog), and Soft Machine (Jazz Rock/Fusion).
http://www.youtube.com/watch?v=ibDLLDOYfmY
http://www.youtube.com/watch?v=mU95bVEQzWw
http://www.youtube.com/watch?v=x544jSXVJUc&feature=related
The last thing I've got up my sleeve are some Alternative/Pyschedelic Hip-Hop groups. The first is called Subtle, and the other is cLOUDDEAD. They're both great, especially in comparison to popular hip-hop.
http://www.youtube.com/watch?v=HgJ3HPnu6hw
http://www.youtube.com/watch?v=s5HVRe7UDuc&ob=av3e
I hope you enjoy some of these.