1. Skyfall -Emotional story and it has some of the best action sequences in the series. It's probably the most thought provoking of the series.
2. Casino Royale -Bond at his most badass IMO. The tension that builds in this movie is insance.
3. The Man With the Golden Gun -The hype for the showdown between these two master assassins
just kept building throughout the movie. Bond shows that he's the best.
4. Goldfinger -Has some of the most iconic fights, scenes, quotes, and villains of any Bond movie.
5. Goldeneye -I really enjoyed this more personal story. Sean Bean is excellent as usual. None of the other Brosnan movies came close to this IMO.