I've spent a lot of my life handing or being involved with caustic/hazardous materials. I don't always know the names of the chemicals themselves, but some of the industries I've worked in were:
Fiberglass moulding
Injection rubber moulding
A fully-loaded machine shop, including handling of various lubricants, coolants and solvents, including some mild acids
And on the side, I used to do a lot of electronics work, which mostly included a lot of soldering. Not sure if mercury is still in that stuff now, but this was a few years ago.
More recently, I've been making tabletop wargaming terrains at home. So for the past few years I have regularly handled various resins, RTV compounds, and all the various chemical agents (releases, hardeners, softeners, etc.) that attend those things.
I guess for me, it's a matter of quantity, rather than caustic quality.