Approximately 1g of potassium cyanide, which was enough to kill about 7 people. Before you get the wrong idea, I'm a chemistry major, and I was working in the achem/pchem storeroom. We were consolidating the waste of last year's independent project, and one student apparently used KCN as their analyte. It might actually have been my former labparter, who was testing apricot kernels (don't go for the alternative cancer treatment, it will kill you.)...
Other fun stuff I've handled: Concentrated nitric acid (as well as putting said into a sealed container and putting that into a 1000W microwave), NaCH3 (will fuck up your DNA), various arsenic and mercury compounds, sodium hydride (worse than any alkali metal), halogenated organics like chloroform and methylene chloride, really nasty organic solvents like acetonitrile, plenty of heavy metal compounds, bromine, tons of concentrated acids, etc.
Oh, fun trivia: the three most commonly used acids are nitric, sulfuric, and hydrochloric. Each one is nasty in its own right, and I don't just mean burning holes into your clothing. Nitric acid is a very potent oxidizer, and hence is used to make explosives (TNT is made with nitric acid and a little bit of sulfuric acid as a catalyst). A mixture of nitric and sulfuric acid is one of the very few compounds capable of oxidizing gold.
Sulfuric acid is the strongest common mineral acid, and will burn holes into just about anything. Given that it is a diprotic acid, it is commonly used in car batteries in conjunction with lead (Pb->PbSO4+2e-).
Hydrochloric acid is actually a gas, and what you get in bottles is just the maximum amount of it that can be dissolved in water. That of course means that some gas will escape if the bottle is heated above 20-25C, or placed in a low pressure environment. If you get the chance, hold a piece of ph paper next to an open container of HCl to try it out.