Definitely watch Trigun. If you liked Cowboy Bebop you'll like Trigun.
Other animes that I think are good are Outlaw Star, Karas (the story is decent but the animation! My god the animation was gorgeous!) and Kurozuka.
If you're looking for something set in the Edo era you might want to give Bakumatsu Kikansetsu Irohanihoheto a go.
Edit: Also forgot to mention Blade of the Immortal. It's also about samurai. The manga is amazing and the anime should be just as good.
Other animes that I think are good are Outlaw Star, Karas (the story is decent but the animation! My god the animation was gorgeous!) and Kurozuka.
If you're looking for something set in the Edo era you might want to give Bakumatsu Kikansetsu Irohanihoheto a go.
Edit: Also forgot to mention Blade of the Immortal. It's also about samurai. The manga is amazing and the anime should be just as good.